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• 秦宗益

  博士

  研究员

  高分子科学与工程系

  博士生导师

  陈彦模、朱美芳课题组

  021-67792861；phqin@dhu.edu.cn

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·社会兼职：

为十几家国际知名刊物担任审稿人，包括Advanced Materials, Energy & Environmental Science, Carbon, ACS Applied Materials & Interfaces, Sensors & Actuators: B. Chemical, Electrochimica Acta, The Journal of Physical Chemistry C, NPG Asia Materials, Nanotechnology, Nanoscale, Chemical Engineering Journal和Cellulose等。

·研究方向:

一、功能材料及传感纤维

二、能量存储与转换材料

三、全生物降解复合材料

·荣誉获奖:

2000年获得中科院院长奖学金优秀奖；2007年上海市科委浦江人才计划

·学习及工作经历:

2000年在中科院长春应用化学研究所获得理学博士学位；曾在中科院长春应用化学研究所国家电化学与光谱分析测试中心、高分子化学与物理国家实验室，复旦大学先进光学材料与器件国家实验室和香港科技大学物理系从事过研究工作；2006年加入欢迎来到公海710纤维材料改性国家重点实验室。已在SCI收录的知名期刊上发表研究论文60余篇，编写专著2章；申请发明专利28项，其中授权发明专利22项，转让2项。

·主讲课程：

研究生课程“现代材料物理化学”；本科生课程“新能源材料”

·已取得的主要研究成果：

(1) 高弹高导的导电纤维的研究。这种新型导电纤维除了新赋予的优异的导电性能以外，还保留着有机纤维基体原有的力学性能，特别是纤维的柔顺性和可编织性，可通过针织、机织编织成织物。这种导电纤维与织物除了具备传统的抗静电与电磁屏蔽功能特性外，还可用来制作纤维应力传感、气体传感、液体传感、光、热传感等多重响应传感器，并在金属离子吸附、催化去污和能量存储以及军事伪装等领域具有潜在的应用前景。

(2) 具有核壳结构的导电高分子、金属氧化物与碳纳米管复合体系的研究。特别注重高有序纳米结构和功能特性的调控和多功能集成。该复合体系可用于超级电容器、太阳能电池、光电纳米器件、传感器等领域。

(3) 生物可降解的纳米纤维材料的研究。高效制备出功能化的棒状与球状纤维素纳米颗粒；开发出一种新型生物可降解的纳米纤维储能材料，具有储能性能高与结构稳定的优点，在温度调节及蓄热保温等领域有着广泛的应用前景；在药物缓释、催化降解等领域也有一定的优势。

·主要论文：

2012年以来发表的研究论文(均为通讯联系人)：

[1] Banglei Liang, ZONGYI QIN, Tao Li, Zhenjun Dou, Fanxin Zeng, Yameng Cai, Zhe Zhou, Meifang Zhu, Poly(aniline–co–pyrrole) on the surface of reduced graphene oxide as high–performance electrode materials for supercapacitors, Electrochimica Acta, 2015 (DOI: 10.1016/j.electacta.2015.01.135)

[2] Tao Li, ZONGYI QIN, Banglei Liang, Fei Tian, Jianyun Zhao, Na Liu, Meifang Zhu, Morphology-dependent capacitive properties of three nanostructured polyanilines through interfacial polymerization in various acidic media, Electrochimica Acta, 2015 (DOI:10.1016/j.electacta.2015.03.169)

[3] Xin Liu, ZONGYI QIN, Zhenjun Dou, Na Liu, Long Chen, Meifang Zhu, Fabricating conductive poly(ethylene terephthalate) nonwoven fabrics by using aqueous dispersion of reduced graphene oxides as sheet dyestuffs, RSC Advances, 4(45), 23869-23875 (2014)

[4] Banglei Liang, ZONGYI QIN, Jianyun Zhao, Yu Zhang, Zhe Zhou, Yaqing Lu, Controlled Synthesis, core–shell structure and electrochemical properties of polyaniline/polypyrrole composite nanofibers, Journal of Materials Chemistry A 2 (1), 251-258 (2014)

[5] Miao Cheng, ZONGYI QIN, Yannan Liu, Yunfeng Qin, Tao Li, Long Chen and Meifang Zhu, Efficient extraction of carboxylated spherical cellulose nanocrystals with narrow distribution through hydrolysis of lyocell fibers by using ammonium persulfate as oxidant, Journal of Materials Chemistry A 2 (1), 251 - 258 (2014)

[6] Houyong Yu, ZONGYI QIN, Surface grafting of cellulose nanocrystals with poly(3-hydroxybutyrate-co-3-hydroxyvalerate), Carbohydrate Polymers, 101: 471–478 (2014)

[7] Houyong Yu, ZONGYI QIN, Banglei Liang, Na Liu, Zhe Zhou, Long Chen, Facile fabrication of thermally stable cellulose nanocrystals with high yield of 93% through hydrochloric acid hydrolysis under hydrothermal condition, Journal of Materials Chemistry A, 1(12): 3938–3944 (2013)

[8] Weinan Xu, ZONGYI QIN, Houyong Yu, Yannan Liu, Na Liu, Zhe Zhou, Long Chen, Cellulose nanocrystals as organic nanofillers for transparent polycarbonate films, Journal of Nanoparticle Research, 15: 1562-1-8 (2013)

[9] Xin Liu, ZONGYI QIN, Xiaolin Zhang, Long Chen, Meifang Zhu, Conductive polypyrrole/polyurethane composite fibers for chloroform gas detection, Advanced Materials Research 750-752: 55-58 (2013)

[10] Fei Tian, ZONGYI QIN，Qian Wu, Na Liu, Yaqing Lu, Effects of reaction conditions on microstructures and properties of polyaniline nanofibers through interfacial polymerization, Advanced Materials Research 750-752: 293-296 (2013)

[11] Jieni Luo, ZONGYI QIN，Qian Wu, Zhe Zhou, Yaqing Lu, Polyaniline nanofibers produced via rapid initiated polymerization in a binary oxidant system, Advanced Materials Research 750-752: 297-300 (2013)

[12] Xiaolin Zhang, ZONGYI QIN, Xin Liu, Banglei Liang, Na Liu, Zhe Zhou, Meifang Zhu, Flexible sensing fibers based on polyaniline–coated polyurethane for chloroform vapor detection, Journal of Materials Chemistry A, 1: 10327-10333 (2013).

[13] Qingqing Fan, ZONGYI QIN, Shanglin Gao, Yongtao Wu, Jürgen Pionteck, Edith Mader, Meifang Zhu, The use of a carbon nanotube layer on a polyurethane multifilament substrate for monitoring strains as large as 400%, Carbon 50(11): 4085-4092 (2012)

[14] Houyong Yu, ZONGYI QIN, Yannan Liu, Long Chen, Na Liu, Zhe Zhou, Simultaneous improvement of mechanical properties and thermal stability of bacterial polyester by cellulose nanocrystals, Carbohydrate Polymers 89(3): 971–978 (2012)

[15] Houyong Yu, ZONGYI QIN, Lingfeng Wang, Zhe Zhou, Crystallization behavior and hydrophobic properties of biodegradable ethyl cellulose-g-poly(3-hydroxybutyrate-co-3-hydroxyvalerate): The influence of the side-chain length and grafting density. Carbohydrate Polymers 87: 2447-2454 (2012)

[16] Qinqing Fan, Xiaolin Zhang, ZONGYI QIN, Preparation of Polyaniline/ Polyurethane Fibers and Their Piezoresistive Property, Journal of Macromolecular Science, Part B: Physics 51(4), 736-746 (2012)

[17] Xiaolin Zhang, ZONGYI QIN, Long Chen, Fabrication of Conductive Polypyrrole/Polyurethane Composite Fibers for Large Strain Sensing, Advanced Materials Research 482-484: 1142-1145 (2012)

[18] Houyong Yu, ZONGYI QIN. Effect of Cellulose nanocrystal on Crystallization Behavior of Poly(3–hydroxybutyrate–co–3–hydroxyvalerate). Advanced Materials Research 430-432: 20-23 (2012)

·主要代表作：

[1] Li Li, ZONGYI QIN, Xia Liang, Qingqing Fan, Yaqing Lu, Wenhua Wu, Meifang Zhu, Facile Fabrication of Uniform Core-Shell Structured Carbon Nanotube-Polyaniline Nanocomposites, The Journal of Physical Chemistry C. 113(14): 5502–5507 (2009) (Cited number: 81)

[2] Yi Zhou, ZONGYI QIN, Li Li, Yu Zhang, Yuling Wei, Lingfeng Wang and Meifang Zhu, Polyaniline/multi-walled carbon nanotube composites with core–shell structures as supercapacitor electrode materials, Electrochimica Acta, 55(12): 3904-3908 (2010) (Cited number: 119)

[3] Qingsheng Liu, Meifang Zhu, Wenhua Wu, ZONGYI QIN, Reducing the formation of six-membered ring ester during thermal degradation of biodegradable PHBV to enhance its thermal stability, Polymer Degradation and Stability, 94(1): 18-24 (2009) (Cited number: 40)

[4] Houyong Yu, ZONGYI QIN, Banglei Liang, Na Liu, Zhe Zhou, Long Chen, Facile fabrication of thermally stable cellulose nanocrystals with high yield of 93% through hydrochloric acid hydrolysis under hydrothermal condition,Journal of Materials Chemistry A, 1(12): 3938–3944 (2013) (Cited number: 30)

[5] Houyong Yu, ZONGYI QIN, Yannan Liu, Long Chen, Na Liu, Zhe Zhou, Simultaneous improvement of mechanical properties and thermal stability of bacterial polyester by cellulose nanocrystals, Carbohydrate Polymers 89(3): 971-978 (2012). (Cited number: 30)

[6] Qingqing Fan, ZONGYI QIN, Tobias Villmow, Jürgen Pionteck, Petra P?tschke, Yongtao Wu, Brigitte Voit, Meifang Zhu, Vapor sensing properties of thermoplastic polyurethane multifilament covered with carbon nanotube networks, Sensors and Actuators B: Chemical, 156(1), 57-61 (2011) (Cited number: 21)

[7] Li Li, ZONGYI QIN, Lingfeng Wang, Hong-Jin Liu, Mei-Fang Zhu, Anchoring alpha-manganese oxide nanocrystallites on multi-walled carbon nanotubes as electrode materials for supercapacitor, J Nanoparticle Research 12(2010)2349–2353 (Cited number: 20)

·授权的专利：

[1] 秦宗益、刘彦男等，一种空心超顺磁性纳米球的制备方法及其应用，ZL 201210513705.4

[2] 秦宗益、刘欣等，一种采用浸染技术制备的导电织物及其应用，ZL 201210454848.2

[3] 秦宗益、刘彦男等，一种羧基化纤维素纳米球及其制备方法，ZL 201210435306.0

[4] 秦宗益、张晓琳等，一种导电复合纤维及其制备方法，ZL 201210437061.5

[5] 秦宗益、余厚咏等，一种纳米银/纤维素纳米晶复合粒子的制备方法，ZL 201210238098.5

[6] 秦宗益，骆洁妮等，一种可卷曲的无支撑碳纳米管气敏膜及其制备方法，ZL 201210105297.9

[7] 秦宗益，张天鹭等，一种单分散聚氨酯/聚吡咯复合纳米弹性球及其制备方法，ZL 201110418203.9

[8] 秦宗益, 余厚咏等，一种纤维素纳米晶增强聚羟基丁酸戊酸酯纳米纤维及其制备方法, ZL201110401211.2

[9] 秦宗益，余厚咏等，一种无溶剂固-固相变储能材料的制备方法，ZL 2011 10159365.5

[10] 秦宗益，范青青等，一种弹性导电复合纤维及其制备方法，ZL 2011 10009585.X

[11] 秦宗益，范青青等，一种三元同轴复合导电纤维及其制备方法，ZL 2011 1 0075961.5

[12] 秦宗益，刘彦男等，一种基于废弃Lyocell纤维制备纤维素纳米球的方法， ZL 201110199585.0

[13] 秦宗益，王凌凤等，一种瓣状二氧化锰纳米晶包覆碳纳米管复合电极材料的制备方法，ZL 2010 10256458.5

[14] 秦宗益，张瑜等，核壳结构的聚苯胺/聚吡咯复合纳米纤维电极材料的制备，ZL 201010228217.X

[15] 秦宗益，余厚咏等，生物可降解的固-固相变纳米纤维或纤维膜的制备方法，ZL 2010 10513771.2

[16] 秦宗益、余厚咏等，一种窄分布纤维素纳米晶制备方法, ZL 201010575030.7

[17] 秦宗益，范青青等，一种柔性碳纳米管-聚氨酯红外敏感薄膜及其制备方法，ZL 200910199519.6

[18] 秦宗益，潘鼎等，无皮芯结构聚丙烯腈基碳纤维原丝的凝胶纺丝原液及其制备, ZL 2009 1 0200222.7

[19] 秦宗益，范青青等，具有高导电率与高弹性及应力传感性能的复合纤维及其制备方法，ZL 2009 1 0046590.0

[20] 秦宗益，朱美芳等，一种原位合成聚羟基脂肪酸酯嵌段共聚物的方法， ZL 2008 1 0207404.2

[21] 秦宗益，李立等，有核壳结构碳纳米管/导电高分子纳米杂化电极材料制备，ZL 2008 1 0207241.8

[22] 刘庆生，秦宗益等，一种高热稳定性聚羟基脂肪酸酯的制备方法，ZL 2007 1 0047278.4

·近几年承担的科研项目：

主持承担了国家自然科学基金“同轴聚吡咯/聚苯胺纳米纤维的生长控制及其储能机理研究”，上海市科委浦江人才计划“基于导电高分子纳米纤维网络的光伏材料设计及智能服装柔性能源的研发”，上海市科委“创新行动计划”项目重大基础项目子课题“高性PANCF纺丝原液热力学及流变行为研究”，上海市科委重点基础项目“自增强型资源可再生生物聚酯纤维的化学设计与梯度结构调控”和教育部高等学校科技创新工程重大项目培育资金“电子信息纤维材料及其智能服装的工程化研究”等项目。还曾主持过一项国家自然科学基金项目和一项国家博士后研究基金项目，并作为研究骨干参加过多项国家自然科学基金项目。